每周分享：Influence of crystal size of HZSM-5 on hydrodeoxygenation of eugenol in aqueous phase

  今天给大家分享的是2014年7月份 《Catalysis Communications》上发表的一篇名为：Influence of crystal size of HZSM-5 on hydrodeoxygenation of eugenol in aqueous phase

  文章摘要如下：

Hydrodeoxygenation of eugenol to hydrocarbons in aqueous phase can be catalyzed by the combination of Pd/C and HZSM-5. In this paper, micro-, submicro- and nano-sized HZSM-5 samples were chosen as catalysts to investigate the influence of crystal size of HZSM-5 on the hydrolysis and dehydration. It was found that the formation rates of hydrocarbons were correlated with the total acidic sites of the submicro- and nano-sized HZSM-5 samples; while for the micro-sized sample, a much lower hydrocarbon formation rate was observed. Meanwhile, HZSM-5 with larger crystal size showed a lower hydrocarbon formation rate even with higher acid density.

   该文章中材料表征采用的是美国麦克仪器AutoChem 2920

   详情可参考下面链接：

http://www.sciencedirect.com/science/article/pii/S1566736714002763