每周分享：Hierarchical Hybrid Organic–Inorganic Materials with Tunable Textural Properties Obtained Using Zeolitic-Layered Precursor

    今天给大家分享的是2014年1月份《Journal of the American Chemical Society》上发表的一篇名为：Hierarchical Hybrid Organic–Inorganic Materials with Tunable Textural Properties Obtained Using Zeolitic-Layered Precursor。

文章摘要如下：

Novel layered zeolitic organic–inorganic materials have been synthesized using a two-dimensional zeolite precursor IPC-1P prepared by a top-down approach from zeolite UTL. The formation of porous materials containing organic linkers or polyhedral oligomeric siloxane covalently bonded to zeolite layers in the interlayer space was confirmed by a variety of characterization techniques (N2/Ar sorption analysis, XRD, 29Si and 13C NMR, TEM). The organic–inorganic porous hybrids obtained by intercalation with silsesquioxane posessed layered morphology and contained large crystalline domains. The hybrids exhibited mesoporous or hierarchical micro-/mesoporous systems, stable up to 350 °C. Textural properties of the formed zeolitic organic–inorganic materials can be controlled by varying the linker or synthetic conditions over a broad range. Surface areas and pore volumes of synthesized hybrids significantly exceed those for parent zeolite UTL and corresponding swollen material; the amount of micropores increased with increasing rigidity and size of the organic linker in the order biphenyl > phenylene > ethanediyl.

    该文章中材料表征采用的是美国麦克仪器ASAP 2020，使用该仪器获得材料-196°C氮气吸附脱附等温线。

详情可参考下面链接：

http://pubs.acs.org/doi/abs/10.1021/ja410844f