顶空气相色谱法检测表面活性剂中二噁烷方法

文献名： Structural, morphological and optical properties of Bi NPs obtained by laser ablation and their selective detection of L-cysteine 作者： Ramon Gabriel Teixeira Rosaa, Celso de Araujo Duartea , Wido Herwig Schreinera, Ney Pereira Mattoso Filhoa, Arandi Ginane Bezerra Jr.b, Andersson Barisonc, Fernanda Maria Marins Ocamposc a Departamento de Física, Universidade Federal do Paraná Centro Politécnico, CP 19044, 81531-990 Curitiba (PR), Brazil b Departamento Acadêmico de Física, Universidade Tecnológica Federal do Paraná, 80230-901 Curitiba (PR), Brazil c Departamento de Química, Universidade Federal do Paraná Centro Politécnico, CP 19081, 81531-990 Curitiba (PR), Brazil 摘要：In the present work we show the results of the investigation of the properties of bismuth nanoparticles (NPs) obtained by the laser ablation in water. The samples were characterized by various techniques: UV/vis spectroscopy, dynamic light scattering, transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, nuclear magnetic resonance and zeta potential. The NPs were metallic and surface oxidated, exhibiting absorption peak at 257 nm due to the surface plasmon resonance. The interaction between the NPs and various amino acids was studied and revealed a selective sensibility to cysteine on a range of concentration from 80 to 720 μM, which we attribute to a dimerization of cysteine to cystine probably complexed to the nanoparticle surface by electrostatic interactions, leading to the modification of the NP absorption spectrum. 关键词：Bismuth; Nanoparticles; Laser ablation; Cysteine

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从中药中提取分离化合物，第一步需要将中药材中的成分用有机溶剂提取出来，包括常规的有机溶剂浸泡，超声提取，超临界提取和加速溶剂萃取（Aseeker-600型加速溶剂萃取仪）等，得到一份总提物。

三维X射线显微镜是当前获取样品内部三维结构最有力的工具之一，而且作为无损的非破坏成像技术，它适用于各种形态的样品，无需包埋，镀层或切片等复杂的样品前处理。布鲁克skyscan系列三维X射线纤维成像系统，包含稳定易用的高分辨率成像设备，功能强大的软件套装，可为不同领域的应用提供完善的解决方案。 我们为大家带来桌面型三维X射线显微镜在药物与医疗器械领域的应用介绍。