超高效液相色谱串联质谱测定乳粉中的喹诺酮残留

文献名： Structural, morphological and optical properties of Bi NPs obtained by laser ablation and their selective detection of L-cysteine 作者： Ramon Gabriel Teixeira Rosaa, Celso de Araujo Duartea , Wido Herwig Schreinera, Ney Pereira Mattoso Filhoa, Arandi Ginane Bezerra Jr.b, Andersson Barisonc, Fernanda Maria Marins Ocamposc a Departamento de Física, Universidade Federal do Paraná Centro Politécnico, CP 19044, 81531-990 Curitiba (PR), Brazil b Departamento Acadêmico de Física, Universidade Tecnológica Federal do Paraná, 80230-901 Curitiba (PR), Brazil c Departamento de Química, Universidade Federal do Paraná Centro Politécnico, CP 19081, 81531-990 Curitiba (PR), Brazil 摘要：In the present work we show the results of the investigation of the properties of bismuth nanoparticles (NPs) obtained by the laser ablation in water. The samples were characterized by various techniques: UV/vis spectroscopy, dynamic light scattering, transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, nuclear magnetic resonance and zeta potential. The NPs were metallic and surface oxidated, exhibiting absorption peak at 257 nm due to the surface plasmon resonance. The interaction between the NPs and various amino acids was studied and revealed a selective sensibility to cysteine on a range of concentration from 80 to 720 μM, which we attribute to a dimerization of cysteine to cystine probably complexed to the nanoparticle surface by electrostatic interactions, leading to the modification of the NP absorption spectrum. 关键词：Bismuth; Nanoparticles; Laser ablation; Cysteine

1、恒温槽采用铝块加热的方式，50~200℃范围内进行高精度温度调节。 2、反应柱分为内径3·5·10mmX长度50·100mm的六个种类，材质分为不锈钢材质和玻璃材质，玻璃反应柱适用于酸性样品的反应。 3、反应柱在恒温槽内的固定操作十分简单，只需一个拉杆动作即可完成安装。 4、样品导入端分为液相反应用和气液反应用2个种类（选购） 5、氢气、氧气、二氧化碳气的气体反应用大流量控制单元也可配备（选购）

市面上有众多的新冠病毒qPCR检测试剂盒，本应用方案采用韩国Seegene公司的AllplexTM 2019-nCoV检测试剂盒在耶拿荧光定量PCR仪 qTOWER³G上进行样品检测，获得符合预期的结果。

Using Bruker’s Hysitron PI 88 SEM PicoIndenter equipped with tilt and rotation stages in conjunction with the QUANTAX EBSD system enables a more robust characterization of metallic materials by combining high resolution phase and grain orientation mapping capabilities with targeted nanomechanical property measurements. This combination could also be used to extend the scope of research related to other advanced textured, anisotropic, or multi-phase materials.