微波辅助聚合物化学

微波辅助聚合物化学：Heck反应， 酯交换反应，Baeyer- Villiger氧化反应，恶唑啉(oxazoline)聚合反应，丙烯酰胺以及多孔材料聚合反应 摘要 若干问题仍然开放论及微波辐射对有机和高分子化学的不同影响。因此, 对相关的调查实验结果进行分析，我们阐明三个微波辐射的主要影响：有效的非接触式加热，加速效果，以及我们专门称的特殊效果。 在本文中，第一: 利用HECK-缩聚反应( HECK-POLYCONDENSATION) 以及通过微波辅助合成聚合物（2, 5-dibutoxy-1, 4-phenylenevinylene)作为一个例子证明微波的 “有效地加热(EFFICIENT HEATING)”。第二: 通过Baeyer–Villiger 反应合成较高内酯的1-oxa-2-oxocyclooctanone and 1-oxa-2-oxocyclononanon作为一个例子证明微波的 “加速效果(ACCELERATING EFFECT)” 。第三:我们最近的调查工作也给予更详细的微波效应的解释，并提供特殊微波效果(SPECIAL MICROWAVE EFFECT)的实例。 Microwave-assisted polymer chemistry: Heck-reaction,transesterification, Baeyer–Villiger oxidation, oxazoline polymerization, acrylamides, and porous materials Abstract—Several questions are still open concerning the different effects of microwave (MW) irradiation in organic and macromolecular chemistry. Analyzing experimental results on a relatively broad investigation area, we came to elucidate three main effects of microwave irradiation: efficient non-contact heating, an accelerating effect, and what we term a special effect. In this paper, we report the first MW assisted synthesis of poly (2, 5-dibutoxy-1, 4-phenylenevinylene) via Heck-polycondensation as an example for efficient heating. The facile synthesis of the higher lactones 1-oxa-2-oxocyclooctanone and 1-oxa-2-oxocyclononanone via Baeyer–Villiger reaction offers indeed an example for theMW-accelerating effect. A survey of our recent work is also given to explain the effects more in detail and to provide examples of the special MWeffect.