Interaction Mechanism of a Novel Polymer Electrolyte Composed of Poly(acrylonitrile), Lithium Triflate, and Mineral Clay
2014-08-19 10:44
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资料摘要:
The addition of optimumcetyl pyridiumchloride (CPC)–modified montmorillonite
(CM) increases the ionic conductivity of poly(acrylonitrile)-based electrolytes
by roughly two orders of magnitude. Specific interactions between the silicate layer, the
nitrile group, and the lithium cation were investigated by FTIR, solid-state NMR,
dielectric analyzer, and alternating current impedance. IR and NMR spectra confirm
that the negative charges in the silicate layers alter the ionic charge environment of the
PAN-based electrolyte composites, which have the same function as the polar group in
PAN. The optimum CM content to achieve the maximum ionic conductivity is 6 phr.
However, untreated montmorillonite leads to insignificant polymer intercalation, the
negative charges in the silicate layers fail to appreciably disturb the attractive force of
the lithium salt, and the resulting conductivity improvement is also less than that of
the CM additives.
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